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The electronic absorption spectra of Fe2+ in non-chromium beryls are examined. Fe2+ in the Al-rich six-coordinate site produces absorption bands at about 820 nm and 970 nm polarizedEc. Fe2+ in the channel produces bands at 820 nm (⊥c) and 2100 nm (‖c). Some blue beryls which are more intensely colored than most aquamarines, have an absorption band at ~700 nm (‖c) which is suggested to arise from an Fe2+/Fe3+ intervalence interaction. Fe2+ in both the six-coordinate site and the channel is identified in the Mössbauer spectra. The Mössbauer spectra of deep blue beryls are unusual and have not been satisfactorily explained. Color changes which accompany heating and irradiation are strongly influenced by the channel iron.  相似文献   
34.
Molecular hydrogen (H(2)) is an important intermediate product and electron donor in microbial metabolism. Concentrations of dissolved H(2) are often diagnostic of the predominant terminal electron-accepting processes in ground water systems or aquatic sediments. H(2) concentrations are routinely measured in ground water monitoring wells but are rarely measured in saturated aquatic sediments due to a lack of simple and practical sampling methods. This report describes the design and development (including laboratory and field testing) of a simple, syringe-based H(2) sampler in (1) saturated, riparian sediments, (2) surface water bed sediments, and (3) packed intervals of a fractured bedrock borehole that are inaccessible by standard pumped methods.  相似文献   
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We report here on the observation and offline detection of the meteotsunami off the New Jersey coast on June 13, 2013, using coastal radar systems and tide gauges. This work extends the previous observations of tsunamis originating in Japan and Indonesia. The radars observed the meteotsunami 23 km offshore, 47 min before it arrived at the coast. Subsequent observations showed it moving onshore. The neighboring tide gauge height reading provides confirmation of the radar observations near the shore.  相似文献   
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Following the statistical analyses of long‐term rainfall‐runoff records from research basins in humid temperate latitudes, Hewlett and co‐workers extended the global challenge to disprove their findings that rainfall intensity was non‐significant. This paper responds to Hewlett's challenge as no preceding analyses have involved forested basins in a tropical cyclone‐prone area. Based on a 7 year rainfall‐runoff record, quickflow (QF), peak flow (QP) and quickflow response ratios (QRR) were regressed as dependent variables against rainfall parameters (intensity, Pi, amount, P), storm duration, D and antecedent flow, I. These data sets were categorised into total streamflow (Q) classes and stratified into three seasons, (monsoon, post‐monsoon and dry) for forested and cleared catchments. Where rainfall variable collinearity met acceptable levels, the addition of Pi to regression models including P, D, I contributed up to 9% and 66% of the respective variations in quickflow and peak flow. For the highest Q storm classes (monsoon), Pi alone accounted for up to 67% and 91% of the variation in QF and QP respectively and was the dominant influence on QP for all seasons. The very high rainfall intensities experienced in the monsoon season is a causal factor why these results differ from those of other research drainage basins. Surprisingly, Pi continued to have a significant influence on QF for dry season classes when less‐intense rainfall occurs. Further the results were similar for both catchments across all seasons. P was the dominant independent variable affecting QF above a threshold Q of 50 mm (monsoon), as rainfall contributes directly to saturation overland flow and return flow under saturated conditions. Further although QRR increased with increasing Q for each season, the regression results for that parameter were poor possibly due to the non‐linearity of the rainfall‐runoff relationship. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
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We present photoelectric photometry of λ And never before published, obtained between February 1982 and December 1990 at 29 different observatories. Then we combine it with all other photometry available to us (previously published, contained in the I.A.U. Commission 27 Archives, and obtained with the Vanderbilt 16-inch automatic telescope but not yet published), to yield a 14.8-year data base. Analysis reveals a long-term cycle in mean brightness, with a full range of 0m.15 and a period of 11.4 ± 0.4 years. Because most of our new photometry was concentrated in the 1983-84 observing season, we analyze that one well-defined light curve with a two-spot model. Spot A keeps a 0m.04 amplitude throughout four rotation cycles whereas the amplitude of spot B diminishes from 0m.09 down almost to 0m.03. The spot rotation periods were 55d.9 ± 0d.6 and 520d.8 ± 1d.0, respectively.  相似文献   
38.
Don Hallett 《Geology Today》2002,18(5):182-185
Just a few kilometres south of Cracow, in southern Poland, the scenery changes abruptly from the fluvial plain of the Vistula river, mantled by tills and loess deposits of the Pleistocene glaciation, to a boldly undulating topography representing the outermost thrust sheet of the Carpathian mountains. These northern foothills of the Carpathians are known in Poland as the Beskid Mountains. The Carpathian thrust front can be traced from Upper Silesia through Cracow and Przemysl in southern Poland as far as the Ukraine and Romania. At several places along the thrust front, salt deposits have been found, which have been mined over many centuries. One of the best known mines is located at Wieliczka, 15 km south-east of Cracow. The mine is a popular tourist location, but it also illustrates some spectacular geological features.  相似文献   
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We investigated phase equilibria in the six-component systemNa2O–K2O–Al2O3–SiO2–F2O–1–H2Oat 100 MPa to characterize differentiation paths of naturalfluorine-bearing granitic and rhyolitic magmas. Topaz and cryoliteare stable saturating solid phases in calcium-poor systems.At 100 MPa the maximum solidus depression and fluorine solubilityin evolving silicic melts are controlled by the eutectics haplogranite–cryolite–H2Oat 640°C and 4 wt % F, and haplogranite–topaz–H2Oat 640°C and 2 wt % F. Topaz and cryolite form a binaryperalkaline eutectic at 660°C, 100 MPa and fluid saturation.The low-temperature nature of this invariant point causes displacementof multiphase eutectics with quartz and alkali feldspar towardsthe topaz–cryolite join and enables the silicate liquidusand cotectic surfaces to extend to very high fluorine concentrations(more than 30 wt % F) for weakly peraluminous and subaluminouscompositions. The differentiation of fluorine-bearing magmasfollows two distinct paths of fluorine behavior, depending onwhether additional minerals buffer the alkali/alumina ratioin the melt. In systems with micas or aluminosilicates thatbuffer the activity of alumina, magmatic crystallization willreach either topaz or cryolite saturation and the system solidifiesat low fluorine concentration. In leucogranitic suites precipitatingquartz and feldspar only, the liquid line of descent will reachtopaz or cryolite but fluorine will continue to increase untilthe quaternary eutectic with two fluorine-bearing solid phasesis reached at 540°C, 100 MPa and aqueous-fluid saturation.The maximum water solubility in the haplogranitic melts increaseswith the fluorine content and reaches 12· 5 ±0· 5 wt % H2O at the quartz–cryolite–topazeutectic composition. A continuous transition between hydrousfluorosilicate melts and solute-rich aqueous fluids is not documentedby this study. Our experimental results are applicable to leucocraticfluorosilicic magmas. In multicomponent systems, however, thepresence of calcium may severely limit enrichment of fluorineby crystallization of fluorite. KEY WORDS: granite; rhyolite; topaz; cryolite; magmatic differentiation  相似文献   
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